B. Morel1, P. Namy2, C. Belhomme1, and I. Crassous3
1Comurhex, Pierrelatte, France
2SIMTEC, Grenoble, France
3LI2C, Paris, France
Modeling electrolysers is a challenge because of the strong coupling between electrical, thermal and CFD equations. Indeed the electrical conductivity of the electrolyte varies with the temperature, which in turn depends on the heat dissipated by the Joule effect and anode over-voltage.In the present study, the fluid velocity values are computed near the electrodes using a diphasic level set ...
R. Hamou, P. Biedermann, M. Rohwerder, and A. Blumeneau
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany
The present work focuses on modeling a new experimental technique: Scanning Electro-chemical Potential Microscopy (SECPM), which is used to probe the potential profile of the electric double layer (EDL). We used an electrostatic approach to compute the EDL potential measured within the metallic probe. Also, we investigated the effect of the interaction of the electrode/probe double layers on the ...
Ziegler, C., Tranitz, M., Schumacher, J.O.
Fraunhofer Institute for Solar Energy Systems, Freiburg, Germany
A mathematical model of planar self-breathing fuel cells is developed and validated. The geometry of the model is a two-dimensional symmetric element of a planar self-breathing fuel cell. The multicomponent transport of the species is considered as well as the couplings between the transport processes of heat, charge, and mass, and the electrochemical reactions. The cell model is validated ...
Pryor Knowledge Systems, Inc.
Bloomfield Hills, MI
Electroplating is a vital technology widely employed for many technological applications ranging from decorative or anti-corrosion coatings to high precision nanotechnology passive electromagnetic cloaking devices. This 2D Axisymmetric Electroplating Model demonstrates one of the modeling methodologies that can be used to calculate the transient generation of a coating thickness of a deposited ...
A. E. Khabbazi, A.J. Richards, and M. Hoorfar
School of Engineering, UBC Okanagan, Kelowna, BC Canada, Canada
Using COMSOL Multiphysics 3.5, a numerical model has been developed to determine the effect of the channel geometry and electrode configuration on cell performance based on polarization curves. The Butler-Volmer equation was implemented to determine the reaction rates at the electrodes. The Conductive Media DC module is used to model the electric fields within the fuel cell.
M. Pfafferodt, P. Heidebrecht, and K. Sundmacher[1,2]
Otto-von-Guericke-University, Magdeburg, Germany
Max-Planck-Institute for Dynamics of Complex Technical Systems, Magdeburg, Germany
A model of a Molten Carbonate Fuel Cell (MCFC) stack with internal reforming is presented. It describes the concentrations in the gas phase, the temperatures and the current densities in this highly integrated system. The differential equations, boundary conditions and the coupling equations used in the model are presented. A strategy to solve the system of partial differential ...
A. Häffelin, J. Joos, M. Ender, A. Weber, and E. Ivers-Tiffée
Institut für Werkstoffe der Elektrotechnik (IWE)
Karlsruher Institut für Technologie (KIT)
A fuel cell is an electrochemical system, which converts chemical energy into electricity by a controlled reaction of hydrogen and oxygen. The performance of the electrode is likewise determined by its material and the microstructure. The simulations were performed directly on reconstructions of real electrodes, obtained from focused ion beam (FIB) tomography. A finite element method (FEM) ...
E. Holzbecher, J. Fuhrmann, R. Halseid, and R.J. Behm
 WIAS, Numerische Analysis, Berlin
 Universität Ulm, Ulm
Two designs for thin layer flow cells were set up at University of Ulm, Germany, in order to identify parameters describing the kinetics of methanol-oxydation – reactions, to be utilized in fuel cells. Computer models for two designs were constructed using COMSOL Multiphysics. Results from the numerical simulations were used to evaluate the different flow cell designs. The aim to ...
Yang, X.1, Zhang, G.1, 2, 3
1 Micro/Nano Bioengineering Laboratory, Department of Biological and Agricultural Engineering
2 Nanoscale Science and Engineering Center
3 Faculty of Engineering, The University of Georgia, Athens, GA 30602, USA
Diffusion controlled redox cycling behavior at nanoscale interdigitated electrodes (IDEs) was simulated using FEMLAB. Cyclic voltammograms were obtained for IDEs with various sizes and spacing, and current collection efficiency and cycling number were calculated. We found that as the size of the IDEs decreased, the shape of the voltammogram changed from a peak-shaped curve to a sigmoidal ...
Department of Mechanical Engineering, University of Michigan – Ann Arbor, Michigan, USA
Polymer electrolyte membrane (PEM) fuel cells have attracted attention as an alternative power source in various applications such as vehicles, portable supplies, and stationary power systems. A non-isothermal PEM fuel model is developed and simulated by using COMSOL Multiphysics. Although PEM fuel cells have been expected to be extensively used as an alternative power source, there have been ...